6-Nitro-o-anisidine → 3-Methoxybenzene-1,2-diamine
反応式
[NH2:1][C:2]1[C:7]([N+:8]([O-])=O)=[CH:6][CH:5]=[CH:4][C:3]=1[O:11][CH3:12]>C(OCC)(=O)C.[Pd]>[NH2:1][C:2]1[C:7]([NH2:8])=[CH:6][CH:5]=[CH:4][C:3]=1[O:11][CH3:12]参加物
4
実験手順
2-Amino-3-nitroanisole (4.3 g) was hydrogenated in ethyl acetate (200 ml) using catalytic 10% palladium on charcoal under an atmosphere of hydrogen at ambient temperature. Once complete the reaction mixture was filtered through Celite and the filtrate evaporated in vacuo to afford the title compound as a brown liquid (3.60 g).
後処理
- customat ambient temperature
- filtrationwas filtered through Celite
- customthe filtrate evaporated in vacuo
出典と根拠
- ORDレコード
- ord-1931361c855c4e49b5bf142cad92b2bd
- 出典データセット
- uspto-grants-2002_03
- 特許番号
- US06353010B1
反応ノート
読み込み中…