反応式
[C:1]([O:4][C:5](=[O:7])[CH3:6])(=[O:3])[CH3:2].[C:8](Cl)(=[O:10])[CH3:9].[H][H]>[Pd].C(O)(=O)C>[C:1]([O:4][CH:5]([O:7][C:8](=[O:10])[CH3:9])[CH3:6])(=[O:3])[CH3:2]参加物
6
実験手順
A 300-ml Fisher-Porter bottle was charged with 61.2 g (0.60 mol) of acetic anhydride, 0.3 g of a 5% palladium-on-carbon catalyst, and 0.8 g of acetyl chloride. The bottle was pressurized to 80-95 psig with hydrogen. After 4 hours at 90° C., a gas chromatographic analysis showed 18% conversion, with about equal amounts of ethylidene diacetate and acetic acid formed.
出典と根拠
- ORDレコード
- ord-dca9bd852fc54eada48f212ce66fe2ed
- 出典データセット
- uspto-grants-1980_09
- 特許番号
- US04221918
関連ノート
読み込み中…