1,3-Di(3-methyl-3-hydroxy-1-butynyl)benzene → Mesitylene

HRID 27801ノート

反応式

HRID 27801 の反応式
[CH3:1]C(O)(C#CC1C=CC=C(Br)C=1)C.CC(O)(C)C#[C:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([C:24]#CC(O)(C)C)[CH:19]=1>>[C:18]1([CH3:17])[CH:19]=[C:20]([CH3:24])[CH:21]=[C:22]([CH3:1])[CH:23]=1

参加物

3

反応物 2

HCID 50980371,3-Di(3-methyl-3-hydroxy-1-butynyl)benzeneHCID 23006378HCID 23006378、化合物

生成物 1

HCID 7947Mesitylene

実験手順

Referring to Table 1 above, the Conversion ("Conv.") was a weight percent conversion and was calculated by: ##EQU1## Selectivity ("Selec.") in Table 1 means, as appropriate: ##EQU2## The Yield means, as appropriate, the yield of 2-methyl-4-(3-bromophenyl)-3-butyn-2-ol: ##STR15## or 1,3-di(3-methyl-3-hydroxy-1-butynyl)benzene: ##STR16## and was calculated as the product of Conversion times Selectivity. Selectivities and yields were calculated only on isolated crude products by gas chromatography with an appropriate internal standard (mesitylene).

後処理

  1. customSelectivities and yields

出典と根拠

ORDレコード
ord-ec37ad1be5cf4fbbb5e7f1bbdb274c51
出典データセット
uspto-grants-1980_09
特許番号
US04223172

反応ノート

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