p-nitrophenol sodium salt → 1-Methoxy-4-[(4-nitrophenoxy)methyl]benzene

HRID 280257

反応式

HRID 280257 の反応式
[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([O-:8])=[CH:6][CH:5]=1)([O-:3])=[O:2].[Na+].[CH3:12][O:13][C:14]1[CH:21]=[CH:20][C:17]([CH2:18]Cl)=[CH:16][CH:15]=1>CN(C=O)C>[CH3:12][O:13][C:14]1[CH:21]=[CH:20][C:17]([CH2:18][O:8][C:7]2[CH:9]=[CH:10][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=2)=[CH:16][CH:15]=1

参加物

4

反応物 2

HCID 13214p-nitrophenol sodium saltHCID 699934-Methyloxybenzyl chloride

生成物 1

HCID 2987451-Methoxy-4-[(4-nitrophenoxy)methyl]benzene

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

To a solution of 24.2 g of sodium p-nitrophenoxide in 60 ml of DMF was added 23.5 g of 4-methoxybenzyl chloride. The precipitate was collected after 24 hours, washed with water, and recrystallized from chloroformcyclohexane, providing 1-methoxy-4-[(4-nitrophenoxy)methyl]benzene, mp 122°-124° C.

後処理

  1. customThe precipitate was collected after 24 hours
  2. washwashed with water
  3. customrecrystallized from chloroformcyclohexane

出典と根拠

ORDレコード
ord-82884560de3541c2b2659bb490b293c7
出典データセット
uspto-grants-1986_05
特許番号
US04588730

関連ノート

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