化工社化工社 化学情報印刷レポート · 研究参考用
p-nitrophenol sodium salt → 1-Methoxy-4-[(4-nitrophenoxy)methyl]benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | p-nitrophenol sodium salt | HCID 13214 | — |
| 反応物 | 4-Methyloxybenzyl chloride | HCID 69993 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 1-Methoxy-4-[(4-nitrophenoxy)methyl]benzene | HCID 298745 | — |
反応手順
To a solution of 24.2 g of sodium p-nitrophenoxide in 60 ml of DMF was added 23.5 g of 4-methoxybenzyl chloride. The precipitate was collected after 24 hours, washed with water, and recrystallized from chloroformcyclohexane, providing 1-methoxy-4-[(4-nitrophenoxy)methyl]benzene, mp 122°-124° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04588730 |
| 出典データセット | uspto-grants-1986_05 |
| ORD ID | ord-82884560de3541c2b2659bb490b293c7 |
| 出典メモ | uspto-grants-1986_05 |