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HRID280257

反应详情

EQUATION

反应方程式

HRID 280257 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1ccc([O-])cc1.[Na+]
HCID13214

Sodium 4-nitrophenolate

C6H4NNaO3

结构：COc1ccc(CCl)cc1
HCID69993

4-Methyloxybenzyl chloride

C8H9ClO

PRODUCTS

生成物

1
结构：COc1ccc(COc2ccc([N+](=O)[O-])cc2)cc1
HCID298745

1-methoxy-4-[(4-nitrophenoxy)methyl]benzene

C14H13NO4

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

To a solution of 24.2 g of sodium p-nitrophenoxide in 60 ml of DMF was added 23.5 g of 4-methoxybenzyl chloride. The precipitate was collected after 24 hours, washed with water, and recrystallized from chloroformcyclohexane, providing 1-methoxy-4-[(4-nitrophenoxy)methyl]benzene, mp 122°-124° C.

WORKUP

后处理

  1. customThe precipitate was collected after 24 hours
  2. washwashed with water
  3. customrecrystallized from chloroformcyclohexane