Ethylene → Cyclohexane, [(trichlorosilyl)methyl]-
反応式
[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH3:5][C:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH:7]=1.C=C>C(Cl)(Cl)Cl>[Cl:1][Si:2]([CH2:5][CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)([Cl:4])[Cl:3]参加物
5
実験手順
A mixture of 20 ml trichlorosilane, 25 ml chloroform, 8.1 g 1-methylcyclohexene and 0.055 g (phenazine)PtCl2 (C2H4) was refluxed and stirred under nitrogen for 6 days. Distillation of the reaction mixture afforded 2.2 g of trichlorosilylmethylcyclohexane C6H11CH2SiCl3 which was characterized by its mass and NMR spectra.
後処理
- temperaturewas refluxed
- distillationDistillation of the reaction mixture
出典と根拠
- ORDレコード
- ord-abc6d32437f54e5ab25df4dc23bd3d26
- 出典データセット
- uspto-grants-1986_05
- 特許番号
- US04588800
反応ノート
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