Triethylamine → HCID 58794783、化合物

HRID 29730

反応式

HRID 29730 の反応式
F[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=1.C1(C)[C:12]([NH2:19])=[C:13]([CH3:18])[C:14](N)=[CH:15][CH:16]=1.C([N:23]([CH2:26][CH3:27])[CH2:24][CH3:25])C>CS(C)=O>[N+:8]([C:5]1[CH:6]=[CH:7][C:2]([NH:19][CH2:12][C:13]2[CH:14]=[CH:15][CH:16]=[C:27]([CH2:26][NH:23][C:24]3[CH:25]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=3)[CH:18]=2)=[CH:3][CH:4]=1)([O-:10])=[O:9]

参加物

5

反応物 3

HCID 8471TriethylamineHCID 9590p-FluoronitrobenzeneHCID 46255812,4-Dimethylbenzene-1,3-diamine

生成物 1

HCID 58794783HCID 58794783、化合物

試薬・触媒・溶媒 1

HCID 679Dimethyl Sulfoxide溶媒

反応条件

温度
60 °C

実験手順

1.73 g of para-fluoronitrobenzene (2 eq.) were dissolved in 5 ml of DMSO. 1.2 equivalents of m-xylenediamine and 4 equivalents of triethylamine were added to the solution. The reaction mixture was heated at 60° C. for 20 hours. The mixture was then poured onto crushed ice and a precipitate formed. The latter was filtered, washed with water, and then dried.

後処理

  1. additionThe mixture was then poured
  2. customonto crushed ice
  3. customa precipitate formed
  4. filtrationThe latter was filtered
  5. washwashed with water
  6. customdried

出典と根拠

ORDレコード
ord-e6dc97c099be42f593855bc0cd045bfe
出典データセット
uspto-grants-2008_09
特許番号
US07422609B2

関連ノート

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