Silicon carbide → 1-Methoxy-2,7-octadiene
反応式
[C-]#[Si+].[CH3:3][O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]>>[CH3:3][O:4][CH2:5][CH:6]=[CH:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12]参加物
3
実験手順
Nitrogen gas was introduced downflow to a 1″×18″ 316 s.s. hot tube reactor system containing 67 ml of silicon carbide (SiC) at a total rate of 6.2 ml/min. The hot tube reactor was heated to 450° C. at which time 1-methoxyoctane (MO), obtained from hydrogenation of 1-methoxy-2,7-octadiene, was added downflow at 0.1 ml/min. Under these conditions 1-methoxyoctane was converted to a mixture of 1-octene and mixed internal octenes at 3.3% wt conversion with a selectivity to 1-octene of 10 m % and mixed internal octenes of 90 m %.
後処理
- additionNitrogen gas was introduced downflow to a 1″×18″ 316 s
出典と根拠
- ORDレコード
- ord-b14c4d5920df40fe8b7b03452914eb2b
- 出典データセット
- uspto-grants-2008_09
- 特許番号
- US07425658B2
反応ノート
読み込み中…