Water → N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine

HRID 31953

反応式

HRID 31953 の反応式
[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][C:17]([C:20]4[CH:25]=[CH:24][C:23]([N:26]([C:30]5[CH:35]=[CH:34][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:32][CH:31]=5)C(=O)C)=[CH:22][CH:21]=4)=[CH:16][CH:15]=3)=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[K+].C(C1C=CC=CC=1CC)C.O>CCCCCC>[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:15]=[CH:16][C:17]([C:20]4[CH:21]=[CH:22][C:23]([NH:26][C:30]5[CH:31]=[CH:32][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:34][CH:35]=5)=[CH:24][CH:25]=4)=[CH:18][CH:19]=3)=[CH:10][CH:9]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

6

反応物 4

HCID 962WaterHCID 86571,2-DiethylbenzeneHCID 14797Potassium HydroxideHCID 59793205N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide

生成物 1

HCID 59793193N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine収率 85.5%

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.

後処理

  1. additionCharged
  2. temperaturerefluxed for 3 days
  3. customthe reaction
  4. waitthe mixture was left
  5. temperaturecooling down
  6. filtrationThe brown solid matter deposited was filtered off
  7. customdried under reduced pressure

出典と根拠

ORDレコード
ord-86bb213d299e42d6ac8e1d5218b776b3
出典データセット
uspto-grants-2008_09
特許番号
US07425654B2

関連ノート

読み込み中…