Allyl bromide → 1-Ferrocenyl-I-methyl-1,3-butadiene
反応式
[CH3:1][C:2]([C-:4]1[CH:8]=[CH:7][CH:6]=[CH:5]1)=O.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14].C(Br)C=C.[I-].[I-].[Sm+2]>>[C-:9]1([C:5]([CH3:6])=[CH:4][CH:2]=[CH2:1])[CH:13]=[CH:12][CH:11]=[CH:10]1.[CH-:4]1[CH:8]=[CH:7][CH:6]=[CH:5]1.[Fe+2:14]参加物
4
実験手順
According to the step flow described in Example 1, about 274 mg (1.20 mmole) of ferrocenyl methyl ketone react with 242 mg (2.0 mmole) of allyl bromide and 1.77 mmole of samarium diiodide in a temperature range of about 0° C. to room temperature to produce an oil-type 1-Ferrocenyl-1-methyl-1,3-butadiene (3b) with a weight of about 302 mg (1.19 mmole) and a yield of about 99%.
出典と根拠
- ORDレコード
- ord-d2cc93ecc2254f4f940d9c3d542781d0
- 出典データセット
- uspto-grants-2001_04
- 特許番号
- US06211392B1
反応ノート
読み込み中…