Thionyl Chloride → 2,4,5-Trimethyl-3-furancarbonyl chloride

HRID 326337

反応式

HRID 326337 の反応式
[CH3:1][C:2]1[O:3][C:4]([CH3:11])=[C:5]([CH3:10])[C:6]=1[C:7](O)=[O:8].S(Cl)([Cl:14])=O>C1(C)C=CC=CC=1>[CH3:1][C:2]1[O:3][C:4]([CH3:11])=[C:5]([CH3:10])[C:6]=1[C:7]([Cl:14])=[O:8]

参加物

4

反応物 2

HCID 24386Thionyl ChlorideHCID 71315072,4,5-Trimethylfuran-3-carboxylic acid

生成物 1

HCID 145359342,4,5-Trimethyl-3-furancarbonyl chloride

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

2,4,5-Trimethyl-3-furancarbonyl chloride was prepared by refluxing 2,4,5-trimethyl-3-furancarboxylic acid (20.0 g) with thionyl chloride (20 ml) in toluene (75 ml) for 3 hours. The toluene and excess thionyl chloride were removed on a rotary evaporator and the residue distilled (b.p. 95°-97° C. at ca. 12 mm).

後処理

  1. customThe toluene and excess thionyl chloride were removed on a rotary evaporator
  2. distillationthe residue distilled (b.p. 95°-97° C. at ca. 12 mm)

出典と根拠

ORDレコード
ord-6e3063683a874e328e6fedbea747620b
出典データセット
uspto-grants-1993_12
特許番号
US05268389

関連ノート

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