化工社化工社 化学情報印刷レポート · 研究参考用
Methyl 9-bromononanoate → (E)-9-[3-(6-Hydroxy-1-hexynyl)-2-(3-methoxy-3-oxo-1-propenyl)phenoxy]nonanoic Acid Methyl Ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl 9-bromononanoate | HCID 554142 | — |
| 反応物 | (E)-3-[2-Hydroxy-6-(6-hydroxy-1-hexynyl)phenyl]-2-propenoic Acid Methyl Ester | HCID 67780365 | — |
| 生成物 | (E)-9-[3-(6-Hydroxy-1-hexynyl)-2-(3-methoxy-3-oxo-1-propenyl)phenoxy]nonanoic Acid Methyl Ester | HCID 67780053 | 71% |
反応手順
Using the procedure of example 122, (E)-3-[2-hydroxy-6-(6-hydroxy-1-hexynyl)phenyl]-2-propenoic acid methyl ester (example 176) was alkylated with methyl 9-bromononanoate giving the title compound, in 71% yield, as a colorless oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05273999 |
| 出典データセット | uspto-grants-1993_12 |
| ORD ID | ord-814f389ddb484e6f8281e2277c0c2323 |
| 出典メモ | uspto-grants-1993_12 |