tert-Butanol → HCID 178435351、化合物
反応式
[CH2:1]([C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][C:12]=1[CH2:13][CH3:14])[C:9](=[O:15])CCC2)[CH3:2].C[C:17]([CH3:20])([O-:19])[CH3:18].[K+].C([OH:26])(C)(C)C>>[CH2:13]([C:12]1[CH:11]=[C:18]2[C:5](=[CH:4][C:3]=1[CH2:1][CH3:2])[C:10](=[O:26])[C:9]([OH:15])=[CH:20][C:17]2=[O:19])[CH3:14]参加物
4
実験手順
Autoxidation of 6,7-diethyl-1-tetralone (48g; 0.24 mole ) with potassium t-butoxide in t-butanol as described in example 8(b) afforded 34.60g (63%) of the title compound. Recrystallisation from aqueous ethanol in the presence of charcoal gave a yellow crystalline solid of m.p. 105°-109° C. (Found; C, 70.45; H, 6.10; C14H14O3 1/2H2O requires; C, 70.28; H, 6.32%).
出典と根拠
- ORDレコード
- ord-0fe69cb552294af6be42deb9d0acceb6
- 出典データセット
- uspto-grants-1977_04
- 特許番号
- US04017639
反応ノート
読み込み中…