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Azobisisobutyronitrile → 4-(Chloromethyl)benzophenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | 4-Methylbenzophenone | HCID 8652 | — |
| 反応物 | Chlorine | HCID 24526 | — |
| 溶媒 | Chlorobenzene | HCID 7964 | — |
| 生成物 | 4-(Chloromethyl)benzophenone | HCID 3016376 | — |
反応手順
196.2 g of 4-methylbenzophenone are dissolved in chlorobenzene and then gassed at 80° C. in the presence of 1.6 g of AIBN (azodiisobutyronitrile) with a total of 71.0 g of chlorine. The reaction mixture is concentrated and the solid material obtained recrystallized from 1 L of ethanol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05859084 |
| 出典データセット | uspto-grants-1999_01 |
| ORD ID | ord-e7340966d1a240309ff577fc36a68f15 |
| 出典メモ | uspto-grants-1999_01 |