Thionyl Chloride → 1,2,2-Trichloro-3,3-dimethylcyclopropanecarboxylic acid chloride

HRID 346251

反応式

HRID 346251 の反応式
[Cl:1][C:2]1([C:9]([OH:11])=O)[C:4]([CH3:6])([CH3:5])[C:3]1([Cl:8])[Cl:7].S(Cl)([Cl:14])=O>>[Cl:1][C:2]1([C:9]([Cl:14])=[O:11])[C:4]([CH3:6])([CH3:5])[C:3]1([Cl:8])[Cl:7]

参加物

3

反応物 2

HCID 24386Thionyl ChlorideHCID 136546961,2,2-Trichloro-3,3-dimethylcyclopropanecarboxylic acid

生成物 1

HCID 136546981,2,2-Trichloro-3,3-dimethylcyclopropanecarboxylic acid chloride

実験手順

The 1,2,2-trichloro-2,2-dimethylcyclopropanecarboxylic acid (3.0 g) synthesized in Example k and thionyl chloride (1.0 ml) were mixed, and reacted at 60° C. The reaction mixture was distilled under reduced pressure to give the desired 1,2,2-trichloro-3,3-dimethylcyclopropanecarboxylic acid chloride (2.8 g) represented by the following formula. ##STR26##

後処理

  1. customreacted at 60° C
  2. distillationThe reaction mixture was distilled under reduced pressure

出典と根拠

ORDレコード
ord-1c052737bb0341df8b9d2564b4ef283f
出典データセット
uspto-grants-1991_10
特許番号
US05061731

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