2-(4-Benzyloxybenzyl)-2-phenoxybutyric acid ethyl ester → HCID 69320315、化合物

HRID 348346ノート

反応式

HRID 348346 の反応式
[CH2:1]([O:3][C:4](=[O:30])[C:5]([CH2:15][C:16]1[CH:21]=[CH:20][C:19]([O:22]CC2C=CC=CC=2)=[CH:18][CH:17]=1)([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[CH2:6][CH3:7])[CH3:2]>C(OCC)(=O)C.[Pd]>[CH2:1]([O:3][C:4](=[O:30])[C:5]([CH2:15][C:16]1[CH:17]=[CH:18][C:19]([OH:22])=[CH:20][CH:21]=1)([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[CH2:6][CH3:7])[CH3:2]

参加物

4

反応物 1

HCID 693525592-(4-Benzyloxybenzyl)-2-phenoxybutyric acid ethyl ester

生成物 1

HCID 69320315HCID 69320315、化合物

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8857Ethyl Acetate溶媒

実験手順

2-(4-Benzyloxybenzyl)-2-phenoxybutyric acid ethyl ester (2.1 mmol) was dissolved in ethyl acetate (30 mL) and treated with 5% palladium on carbon (300 mg), and stirred under an atmosphere of hydrogen for 20 h. The suspension was filtered through celite and concentrated in vacuo to an oil.

後処理

  1. filtrationThe suspension was filtered through celite and
  2. concentrationconcentrated in vacuo to an oil

出典と根拠

ORDレコード
ord-d89504f04e2c4c2a9509b7f36739a44e
出典データセット
uspto-grants-2007_02
特許番号
US07176224B2

反応ノート

読み込み中…