Iodobenzene → 3-methyl-N,N-diphenylaniline

HRID 35014ノート

反応式

HRID 35014 の反応式
I[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([NH:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:10]=1>[Cu]>[CH3:8][C:9]1[CH:10]=[C:11]([N:15]([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:12]=[CH:13][CH:14]=1

参加物

4

反応物 2

HCID 11575IodobenzeneHCID 14569N-(3-Methylphenyl)aniline

生成物 1

HCID 110864773-methyl-N,N-diphenylaniline収率 75%

試薬・触媒・溶媒 1

HCID 23978Copper触媒

実験手順

The same equipment and conditions as in example I were employed with the following charge: 20.4 grams (0.1 mole) iodobenzene, 27.5 grams (0.15 mole) 3-methyldiphenylamine, 15.0 grams copper powder and 30.0 milliliters of Soltrol® 170. The above-identified intended product was obtained as colorless crystals having a melting point of 69°-70° C. Yield 75%.

後処理

  1. additionfollowing charge
  2. customThe above-identified intended product was obtained as colorless crystals

出典と根拠

ORDレコード
ord-b130051439054dada6006afe8ea910ee
出典データセット
uspto-grants-1988_08
特許番号
US04764625

反応ノート

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