Sodium Hydroxide → 4-Hydroxyphenylsulfonic acid disodium salt

HRID 351020ノート

反応式

HRID 351020 の反応式
O.O.[Na+:3].[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:13])=[O:12])=[CH:7][CH:6]=1.[OH-].[Na+]>C1(C)C=CC=CC=1>[Na+:3].[Na+:3].[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:12])=[O:13])=[CH:7][CH:6]=1.[OH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([O-:14])(=[O:12])=[O:13])=[CH:7][CH:6]=1

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 23666329Sodium P-phenolsulfonate dihydrate

生成物 1

HCID 195991314-Hydroxyphenylsulfonic acid disodium salt収率 126.5%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A solution of 4-hydroxybenzenesulfonic acid sodium salt dihydrate (20 g, 86 mmol) in 1N aqueous sodium hydroxide (86 mL, 86 mmol) is stirred and heated at 50–60° C. for 1 hour. The solution is concentrated in vacuo at 50° C. to give a solid. The solid is suspended in anhydrous toluene and concentrated in vacuo. This process is repeated twice. The solid is dried at 50° C. at high vacuum for 18 hours to give 21.34 g of 4-hydroxybenzenesulfonic acid disodium salt.

後処理

  1. temperatureheated at 50–60° C. for 1 hour
  2. concentrationThe solution is concentrated in vacuo at 50° C.
  3. customto give a solid
  4. concentrationconcentrated in vacuo
  5. customThe solid is dried at 50° C. at high vacuum for 18 hours

出典と根拠

ORDレコード
ord-bfa9679dccda4c6384a65e667bc80767
出典データセット
uspto-grants-2007_02
特許番号
US07183304B2

反応ノート

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