Phloroglucinol → Bisphenol P

HRID 354523

反応式

HRID 354523 の反応式
[C:1]1([CH:9]=[C:7]([OH:8])[CH:6]=[C:4](O)[CH:3]=1)O.CC(C1C=CC(O)=CC=1)([CH2:22][C:23]([CH3:32])([C:25]1[CH:30]=[CH:29][C:28]([OH:31])=[CH:27][CH:26]=1)[CH3:24])CC(C1C=CC(O)=CC=1)C.OC1[CH:46]=[CH:45][C:44]([C:47]2[CH:52]=C(C3C=CC(O)=CC=3)C=C(C3C=CC(O)=CC=3)[CH:48]=2)=[CH:43][CH:42]=1.OC1C=CC(C(C2C=CC(O)=CC=2)(C2C=CC(O)=CC=2)C)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2)(C2C=CC(O)=CC=2)C2C=CC=CC=2)=CC=1.OC1C=C(O)C=CC=1C(O)=O.OC1C=CC(C(C2C=CC(O)=CC=2O)(C)C)=CC=1>>[OH:31][C:28]1[CH:27]=[CH:26][C:25]([C:23]([C:22]2[CH:46]=[CH:45][C:44]([C:47]([C:3]3[CH:4]=[CH:6][C:7]([OH:8])=[CH:9][CH:1]=3)([CH3:52])[CH3:48])=[CH:43][CH:42]=2)([CH3:32])[CH3:24])=[CH:30][CH:29]=1

参加物

8

反応物 7

HCID 359PhloroglucinolHCID 14912,4-Dihydroxybenzoic AcidHCID 931181,1,1-Tris(4-hydroxyphenyl)ethaneHCID 3481481,3,5-Tris(4-hydroxyphenyl)benzeneHCID 17820215Tri-(4-hydroxyphenyl)-phenyl methaneHCID 218855202-(4-Hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propaneHCID 218944334,6-Dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane

生成物 1

HCID 630355Bisphenol P

実験手順

The polycarbonates may, of course, be branched by incorporating small quantities of polyhydroxyl compounds, e.g. 0.05 to 2.0 mols percent (based on the quantity of bisphenols). Polycarbonates of this kind have been described, e.g. in German Offenlegungsschriften No. 1,570,533; 2,116,974 and 2,113,347, in British Patents No. 885,442 and 1,079,821 and in U.S. Pat. No. 3,544,514. The following are some of the polyhydroxyl compounds which are suitable for this purpose: Phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene-(2), 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl-methane, 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenyl-4-isopropyl)-phenol,2,6-bis-(2'-hydroxy-5'-methyl-benzyl)-4-methylphenol, 2,4-dihydroxybenzoic acid, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4',40"-dihydroxytriphenyl-methyl)-benzene.

出典と根拠

ORDレコード
ord-6ada6bb5c4e344879e79e1c331e424be
出典データセット
uspto-grants-1983_03
特許番号
USRE031165

関連ノート

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