4-Octylaniline → N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

HRID 359305

反応式

HRID 359305 の反応式
[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)[CH:18]=[C:17]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)[O+]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:41]1[CH:47]=[CH:46][C:44]([NH2:45])=[CH:43][CH:42]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:41]1[CH:42]=[CH:43][C:44]([N+:45]2[C:15]([C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:20][C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:18][C:17]=2[C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[CH:46][CH:47]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]

参加物

4

反応物 2

HCID 853464-OctylanilineHCID 2778031AG-G-77560

生成物 1

HCID 20064818N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A 4.58-g portion (0.01 mole) of 2,4,6-triphenylpyrylium triflate is added to 200 ml of ethanol. To this solution, 2.05 g (0.01 mole) of p-n-octylaniline is added. The mixture is refluxed for about 20 hours. Upon removing the ethanol by rotating evaporation, an orange oil remains. To remove the last of the ethanol the oil is placed under high vacuum.

後処理

  1. temperatureThe mixture is refluxed for about 20 hours
  2. customUpon removing the ethanol
  3. customevaporation
  4. customTo remove the last of the ethanol the oil

出典と根拠

ORDレコード
ord-7852d11320734bafb0ba94ae0caa2fb1
出典データセット
uspto-grants-1991_03
特許番号
US05000873

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