4-Dodecylaniline → HCID 20064821、化合物

HRID 359306

反応式

HRID 359306 の反応式
[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19](C3C=CC=CC=3)C=C(C3C=CC=CC=3)[O+]=2)[CH:14]=C[CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:45]1[CH:51]=[CH:50][C:48]([NH2:49])=[CH:47][CH:46]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:45]1[CH:46]=[CH:47][C:48]([N+:49]2[C:20]([CH3:19])=[CH:15][C:9]([CH3:14])=[CH:10][C:11]=2[CH3:12])=[CH:50][CH:51]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]

参加物

4

反応物 2

HCID 77014-DodecylanilineHCID 2778031AG-G-77560

生成物 1

HCID 20064821HCID 20064821、化合物

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A 2.3-g portion (0.005 mole) of 2,4,6-triphenylpyrylium triflate is placed in a 500-ml round-bottom flask. To this, 200 ml of ethanol is added and then 1.3 g (0.005 mole) of p-dodecylaniline is added. The mixture is refluxed for about 20 hours. The ethanol is removed by evaporation to give a yellow waxy substance. This material is washed with ether which causes some yellow crystals to precipitate.

後処理

  1. temperatureThe mixture is refluxed for about 20 hours
  2. customThe ethanol is removed by evaporation
  3. customto give a yellow waxy substance
  4. washThis material is washed with ether which
  5. customto precipitate

出典と根拠

ORDレコード
ord-7f3fcc1c6d9047fca8c49414a0df1a8c
出典データセット
uspto-grants-1991_03
特許番号
US05000873

関連ノート

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