Ethanol → Benzeneethanol, 4-(acetyloxy)-
反応式
[O:1]1[CH2:3][CH2:2]1.C([O:7][CH:8]=[CH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=O)C.C([OH:18])C>[Cr].[Co].[Pd]>[C:3]([O:1][C:13]1[CH:12]=[CH:11][C:10]([CH2:9][CH2:8][OH:7])=[CH:15][CH:14]=1)(=[O:18])[CH3:2]参加物
5
実験手順
A 300 ml Fluitron autoclave (Hastelloy C) is charged with 69.5 g crude acetoxystyrene oxirane (86%; 0.335 mol), 200 ml ethanol and 1.6 g Pd/C (5% Pd on carbon; 47.8% H2O). After sealing, the stirrer is started, and the autoclave purged with nitrogen and hydrogen and then pressurized to 400 psig with hydrogen. The H2 pressure is kept constant during the one hour reaction period. The autoclave is vented and purged with N2. The reaction mixture is sucked out of the reactor (63.2 g ethanol rinse) and filtered (23.7 g ethanol rinse).
後処理
- customthe autoclave purged with nitrogen and hydrogen
- customThe H2 pressure is kept constant during the one hour reaction period
- custompurged with N2
- washThe reaction mixture is sucked out of the reactor (63.2 g ethanol rinse)
- filtrationfiltered
- wash(23.7 g ethanol rinse)
出典と根拠
- ORDレコード
- ord-383f67091eb74353b8e2be52883afc64
- 出典データセット
- uspto-grants-1991_03
- 特許番号
- US05003115
反応ノート
読み込み中…