Nitric Acid → 2-Amino-3,5-dinitropyridine
反応式
[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N:3]=1.[N+:11]([O-])([OH:13])=[O:12]>OS(O)(=O)=O>[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5]([N+:11]([O-:13])=[O:12])=[CH:4][N:3]=1参加物
4
実験手順
To a stirred solution of 2-amino-3-nitropyridine in conc. H2SO4 (50 mL) at 0° C. was added HNO3 (3.10 mL, d=1.49) dropwise over 10 min. The mixture was warmed to r.t. for 20 min then heated to 50° C. for 90 min. The reaction mixture was cooled and poured into 400 g of ice. The resulting precipitate was filtered and air dried to give 10.3 g of 2-amino-3,5-dinitropyridine as a yellow solid.
後処理
- temperaturethen heated to 50° C. for 90 min
- temperatureThe reaction mixture was cooled
- filtrationThe resulting precipitate was filtered
- customair dried
出典と根拠
- ORDレコード
- ord-4b811c4440df4bf9ab817db4d5ed5ede
- 出典データセット
- uspto-grants-1995_05
- 特許番号
- US05412097
反応ノート
読み込み中…