HCID 67598507、化合物 → HCID 67598837、化合物
反応式
[F:1][C:2]1[C:7]([C:8]#[C:9][Sn:10]([CH2:19][CH2:20][CH2:21][CH3:22])([CH2:15][CH2:16][CH2:17][CH3:18])[CH2:11][CH2:12][CH2:13][CH3:14])=[CH:6][CH:5]=[CH:4][N:3]=1>C1COCC1.CCCCCC>[F:1][C:2]1[C:7](/[CH:8]=[CH:9]\[Sn:10]([CH2:11][CH2:12][CH2:13][CH3:14])([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:15][CH2:16][CH2:17][CH3:18])=[CH:6][CH:5]=[CH:4][N:3]=1参加物
4
実験手順
To a suspension of Cp2ZrHCl (2.58 g) in dry THF (50 mL) was added 2-fluoro-3-(tributylstannylethynyl)pyridine (2.05 g). After 2 hours the mixture was diluted with hexane and filtered through a short silica gel column. Evaporation of the solvents gave Z-2-fluoro-3-(2-tributylstannylethenyl)pyridine as an oil (1.72 g).
後処理
- filtrationfiltered through a short silica gel column
- customEvaporation of the solvents
出典と根拠
- ORDレコード
- ord-6757c9f895f747f8992d675ec6608380
- 出典データセット
- uspto-grants-1999_02
- 特許番号
- US05869482
反応ノート
読み込み中…