Phthalonitrile → Phthalocyanine

HRID 363710

反応式

HRID 363710 の反応式
[CH:1]1[CH:6]=[C:5]([C:7]#[N:8])[C:4]([C:9]#[N:10])=[CH:3][CH:2]=1>[Ti](Cl)(Cl)(Cl)Cl.ClC1C2C(=CC=CC=2)C=CC=1>[CH:1]1[CH:2]=[CH:3][C:4]2[C:5](=[C:7]3[N:8]=[C:7]4[N:10]=[C:9]([C:4]5[CH:3]=[CH:2][CH:1]=[CH:6][C:5]=54)[N:10]=[C:9]4[NH:8][C:7]([C:5]5[CH:6]=[CH:1][CH:2]=[CH:3][C:4]=54)=[N:10][C:9]4=[N:8][C:7]([C:5]5[CH:6]=[CH:1][CH:2]=[CH:3][C:4]=54)=[N:10][C:9]=2[NH:8]3)[CH:6]=1

参加物

4

反応物 1

HCID 7042Phthalonitrile

生成物 1

HCID 86280045Phthalocyanine

試薬・触媒・溶媒 2

HCID 24193Titanium Tetrachloride触媒HCID 70031-Chloronaphthalene溶媒

実験手順

In this comparative example, α-titanyloxyphthalocyanine was prepared by the method disclosed in Japanese Patent Application Laying-open No.62-134651. That is, a mixture of 40 g of phthalodinitrile, 18 g of titanium tetrachloride, and 500 cc of chloronaphthalene was stirred at the temperature of 240° C. to 250° C. for 3 hours in nitrogenous atmosphere to completely react with each other. The mixture was filtrated after the reaction, and as a result dichlorothitanium phthalocyanine was obtained. The obtained dichlorothitanium was mixed with 300 cc of concentrated ammonium solution to obtain a mixture. Then the mixture was heat-refluxed for 1 hour and subjected to the purification by using a Soxhlet extractor. Consequently, titanyloxyphthalocyanine was obtained by drying the purified product. The resultant titanyloxyphthalocyanine was confirmed as α-type crystal having an X-ray diffraction spectrum which is the same as the one shown in FIG. 3.

後処理

  1. customto completely react with each other
  2. filtrationThe mixture was filtrated
  3. customafter the reaction

出典と根拠

ORDレコード
ord-22bf60cda7144d808e529c5e8e761ca4
出典データセット
uspto-grants-1999_02
特許番号
US05874570

関連ノート

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