Glyphosate → N-tert-Butylglycine

HRID 363807

反応式

HRID 363807 の反応式
C(NCP(O)(O)=O)C(O)=O.[C:11]([N:15](CP(O)(O)=O)[CH2:16][C:17]([OH:19])=[O:18])([CH3:14])([CH3:13])[CH3:12].C(N)(C)(C)C>>[C:11]([NH:15][CH2:16][C:17]([OH:19])=[O:18])([CH3:14])([CH3:13])[CH3:12]

参加物

4

実験手順

Gaertner, U.S. Pat. No. 3,927,080, describes the production of glyphosate by acid hydrolysis and dealkylation of N-t-butyl-N-phosphonomethylglycine or its esters. Tertiary butyl amine is reacted with a bromoacetate ester to produce an ester of N-t-butylglycine, which is in turn reacted with formaldehyde and phosphorous acid to produce the N-t-butyl-N-phosphonomethylglycine precursor.

出典と根拠

ORDレコード
ord-86053d540300417b91824d235673d37d
出典データセット
uspto-grants-1999_02
特許番号
US05874612

関連ノート

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