Silver Nitrate → Silver Hexadecylsulfinate

HRID 364685ノート

反応式

HRID 364685 の反応式
[CH2:1]([S:17]([O-:19])=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[Na+].[Ag:21].[Ag]=S.[Ag]Cl.[N+]([O-])(O)=O.O.[N+]([O-])([O-])=O.[Ag+]>O>[CH2:1]([S:17]([O-:19])=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[Ag+:21]

参加物

7

反応物 5

HCID 24470Silver NitrateHCID 24561Silver ChlorideHCID 22472390Nitric acid monohydrateHCID 22981889Silver sulfide (Ag2S)HCID 23682398Sodium hexadecylsulfinate

生成物 1

HCID 13725603Silver Hexadecylsulfinate

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

Taking material from Example 1, eight grams of sodium hexadecylsulfinate (0.026 moles) was dissolved in 300 ml deionized water at 45° to 50° C. When measured at 45° C. the pH was 9.0 and the millivolt reading, using a silver/silver sulfide electrode and a silver chloride/4M KCl reference electrode, was -24. The pH was adjusted to 6.9 with 1:20 HNO3 /H2O. A solution of 7 ml 3N AgNO3 and 200 ml H2O was added with stirring to this mixture in four portions of 50 ml each, stirring 2 minutes after each addition, and stirring 10 minutes after the final addition. Temperature was maintained at 40° to 45° C. The final mixture had a pH of 3.6 and a millivolt reading of +206 at 40° C. This corresponds to a pAg of 6.4.

後処理

  1. dissolutionwas dissolved in 300 ml
  2. customat 45° to 50° C
  3. custommeasured at 45° C.
  4. stirringstirring 2 minutes
  5. additionafter each addition
  6. stirringstirring 10 minutes after the final
  7. additionaddition
  8. temperatureTemperature was maintained at 40° to 45° C
  9. customof +206 at 40° C

出典と根拠

ORDレコード
ord-a5845e529b9d4f19b0fc457143892d40
出典データセット
uspto-grants-1986_08
特許番号
US04605753

反応ノート

読み込み中…