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Phenol → 2-Decylthio-3-hydroxynorbornane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phenol | HCID 996 | — |
| 反応物 | 1-Decanethiol | HCID 8917 | — |
| 反応物 | exo-2,3-Epoxynorbornane | HCID 18463 | — |
| 反応物 | Phosphoric triamide, tris[tris(dimethylamino)phosphoranylidene]- | HCID 9829709 | — |
| 溶媒 | Hexamethylphosphorous triamide | HCID 15355 | — |
| 生成物 | 2-Decylthio-3-hydroxynorbornane | HCID 10221481 | 95% |
反応手順
A reaction was conducted as described in Example 1 except that tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide was replaced with the same molar amount of a partially hydrated tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide, [(Me2N)3P=N]3P=O.0.29H2O, phenol was replaced with the same molar amount of decanethiol and PGE was replaced with 2,3-epoxynorbornane. Desired 2-decylthio-3-hydroxynorbornane was formed in an analytical yield of 95% and isolated in a yield of 90%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06130346 |
| 出典データセット | uspto-grants-2000_10 |
| ORD ID | ord-307063b2ab434fabb0a5c3ee1233789e |
| 出典メモ | uspto-grants-2000_10 |