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HRID366918

反应详情

EQUATION

反应方程式

HRID 366918 的结构方程式

REACTANTS

反应物

4
结构：Oc1ccccc1
HCID996

Phenol

C6H6O

结构：CCCCCCCCCCS
HCID8917

1-Decanethiol

C10H22S

结构：C1CC2CC1C1OC21
HCID18463

2,3-Epoxynorbornane

C7H10O

结构：CN(C)P(=NP(=O)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C
HCID9829709

Phosphoric triamide, tris[tris(dimethylamino)phosphoranylidene]-

C18H54N12OP4

PRODUCTS

生成物

1
结构：CCCCCCCCCCSC1C2CCC(C2)C1O
HCID10221481

未命名化合物

收率 95%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)P(N(C)C)N(C)C
溶剂HCID15355

Phosphorous triamide, hexamethyl-

C6H18N3P

PROCEDURE

实验过程

A reaction was conducted as described in Example 1 except that tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide was replaced with the same molar amount of a partially hydrated tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide, [(Me2N)3P=N]3P=O.0.29H2O, phenol was replaced with the same molar amount of decanethiol and PGE was replaced with 2,3-epoxynorbornane. Desired 2-decylthio-3-hydroxynorbornane was formed in an analytical yield of 95% and isolated in a yield of 90%.