Tris(pentafluorophenyl)borane → Tris(pentafluorophenyl)borane hydrate

HRID 36756

反応式

HRID 36756 の反応式
[B:1]([C:24]1[C:33]([F:34])=[C:31]([F:32])[C:29]([F:30])=[C:27]([F:28])[C:25]=1[F:26])([C:13]1[C:22]([F:23])=[C:20]([F:21])[C:18]([F:19])=[C:16]([F:17])[C:14]=1[F:15])[C:2]1[C:11]([F:12])=[C:9]([F:10])[C:7]([F:8])=[C:5]([F:6])[C:3]=1[F:4].[OH2:35].O.O.B(C1C(F)=C(F)C(F)=C(F)C=1F)(C1C(F)=C(F)C(F)=C(F)C=1F)C1C(F)=C(F)C(F)=C(F)C=1F>ClCCl>[B:1]([C:13]1[C:22]([F:23])=[C:20]([F:21])[C:18]([F:19])=[C:16]([F:17])[C:14]=1[F:15])([C:24]1[C:33]([F:34])=[C:31]([F:32])[C:29]([F:30])=[C:27]([F:28])[C:25]=1[F:26])[C:2]1[C:3]([F:4])=[C:5]([F:6])[C:7]([F:8])=[C:9]([F:10])[C:11]=1[F:12].[OH2:35]

参加物

4

反応物 2

HCID 582056Tris(pentafluorophenyl)boraneHCID 11261567Borane, tris(pentafluorophenyl)-, trihydrate

生成物 1

HCID 15875499Tris(pentafluorophenyl)borane hydrate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

A mixture of 0.566 gram (1 mmol) (C6F5)3B.3H2O as prepared in Example 1 and 1.024 grams (2 mmol) (C6F5)3B in 10 mL dichloromethane was stirred for 15 minutes and then evaporated to dryness under vacuum. A quantitative yield of the product remained and was stored under dry nitrogen.

後処理

  1. customevaporated to dryness under vacuum

出典と根拠

ORDレコード
ord-947c77284e834395add5a41dba46ce12
出典データセット
uspto-grants-1995_05
特許番号
US05416177

関連ノート

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