Sodium Iodide → HCID 10988867、化合物
反応式
[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9]Cl)(=[O:3])[CH3:2].[I-:11].[Na+]>CC(C)=O>[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][I:11])(=[O:3])[CH3:2]参加物
4
実験手順
5-Chloropentyl acetate (26.5 g, 0.16 mol) was added to a solution of sodium iodide (45 g, 0.30 mol) in dry acetone (200 ml). The resulting pale yellow solution was heated at reflux for 65 h, during which time a white solid separated (sodium chloride). The final mixture was cooled to room temperature and filtered to remove the NaCl, which was washed with acetone and diethyl ether, then dried under vacuum at 50° C. Expected yield of NaCl=9.4 g; isolated yield=9.47 g (100%).
後処理
- temperatureThe resulting pale yellow solution was heated
- temperatureat reflux for 65 h, during which time a white solid
- customseparated (sodium chloride)
- filtrationfiltered
- customto remove the NaCl, which
- washwas washed with acetone and diethyl ether
- customdried under vacuum at 50° C
- customisolated yield=9.47 g (100%)
出典と根拠
- ORDレコード
- ord-653cf5ff72bd4a6da6bf45a68d819e95
- 出典データセット
- uspto-grants-2000_10
- 特許番号
- US06140494
反応ノート
読み込み中…