Atrazine → Atraton

HRID 370610

反応式

HRID 370610 の反応式
CCNC1N=C(Cl)N=C(NC(C)C)N=1.C[O-].[Na+].[CH3:18][O:19][C:20]1[N:25]=[C:24]([NH:26][CH:27]2[CH2:29][CH2:28]2)[N:23]=[C:22]([NH:30][CH:31](C)[CH3:32])[N:21]=1.ClC1N=C(NC2CC2)N=C(NC(C)C)N=1>CCCCCC>[CH3:18][O:19][C:20]1[N:25]=[C:24]([NH:26][CH:27]([CH3:29])[CH3:28])[N:23]=[C:22]([NH:30][CH2:31][CH3:32])[N:21]=1

参加物

6

反応物 4

HCID 2256AtrazineHCID 24738CyprazineHCID 10942334Sodium MethoxideHCID 202748622-Methoxy-4-(cyclopropylamino)-6-(1-methylethylamino)-1,3,5-triazine

生成物 1

HCID 15359Atraton

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

2-methoxy-4-(1-methylethylamino)-6-ethylamino-1,3,5-triazine (14A) (Atraton) was prepared as a white solid (recrystallized from hexane), m.p.: 95°-96° C., by treating atrazine (Examples 5-8) with sodium methoxide according to the procedure described for preparing 13A from 9B, Example 13.

出典と根拠

ORDレコード
ord-472066d724e641529f689e4d8224ee70
出典データセット
uspto-grants-1985_07
特許番号
US04528027

関連ノート

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