Thionyl Chloride → 12-Benzyloxy-2,2-dimethyldodecanoyl chloride

HRID 371267ノート

反応式

HRID 371267 の反応式
S(Cl)([Cl:3])=O.[CH2:5]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([CH3:28])([CH3:27])[C:24](O)=[O:25])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>C1C=CC=CC=1>[CH2:5]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([CH3:28])([CH3:27])[C:24]([Cl:3])=[O:25])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

参加物

4

反応物 2

HCID 24386Thionyl ChlorideHCID 1347828912-Benzyloxy-2,2-dimethyldodecanoic acid

生成物 1

HCID 1347827612-Benzyloxy-2,2-dimethyldodecanoyl chloride

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

1.2 ml of thionyl chloride was added to a solution of 3.34 g of the obtained carboxylic acid in 5 ml of anhydrous benzene, and the mixture was reacted at room temperature for 12 hours. The reaction mixture was concentrated under reduced pressure to give 3.53 g of 12-benzyloxy-2,2-dimethyldodecanoyl chloride as a colorless oily material.

後処理

  1. customthe mixture was reacted at room temperature for 12 hours
  2. concentrationThe reaction mixture was concentrated under reduced pressure

出典と根拠

ORDレコード
ord-133f650a68434f0f9bf6bf8e6f58dcf8
出典データセット
uspto-grants-1985_07
特許番号
US04530794

反応ノート

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