3-Bromoaniline → 2,2'-Dithiobis[N-(3-bromophenyl)benzamide]

HRID 3713

反応式

HRID 3713 の反応式
[C:1](Cl)(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[S:8][S:9][C:10]1[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=1[C:12](Cl)=[O:13].[Br:21][C:22]1[CH:23]=[C:24]([CH:26]=[CH:27][CH:28]=1)[NH2:25]>ClCCl.N1C=CC=CC=1>[Br:21][C:22]1[CH:23]=[C:24]([NH:25][C:1](=[O:19])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=2[S:8][S:9][C:10]2[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=2[C:12]([NH:25][C:24]2[CH:26]=[CH:27][CH:28]=[C:22]([Br:21])[CH:23]=2)=[O:13])[CH:26]=[CH:27][CH:28]=1

参加物

5

反応物 2

HCID 115623-BromoanilineHCID 881642,2'-Dithiodibenzoyl chloride

生成物 1

HCID 189353082,2'-Dithiobis[N-(3-bromophenyl)benzamide]収率 55.8%

試薬・触媒・溶媒 2

HCID 1049Pyridine溶媒HCID 6344Dichloromethane溶媒

実験手順

This compound was prepared according to the general method of Example 77 using 2,2'-dithiobisbenzoyl chloride (2.00 g, 5.83 mmol) in 50 mL of dichloromethane and 3-bromoaniline (1.98 g, 11.6 mmol) in 16 mL of pyridine. The crude product was recrystallized from ethyl acetate-hexanes to yield 1.99 g of the title compound, mp 194°-196° C.

後処理

  1. customThis compound was prepared
  2. customThe crude product was recrystallized from ethyl acetate-hexanes

出典と根拠

ORDレコード
ord-b72f28adf1044fce8dbba03ec99cbcd2
出典データセット
uspto-grants-1998_03
特許番号
US05734081

関連ノート

読み込み中…