m-Chloroperbenzoic acid → HCID 12453357、化合物
反応式
C([C:4]1[CH:17]=[CH:16][C:15]2[C:14]3[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=3)[CH:8]=[CH:7][C:6]=2[CH:5]=1)(=O)C.ClC1C=[C:21](C=CC=1)[C:22]([O:24]O)=[O:23]>C(Cl)Cl>[C:22]([O:24][C:4]1[CH:17]=[CH:16][C:15]2[C:10]3[C:9](=[CH:14][CH:13]=[CH:12][CH:11]=3)[CH:8]=[CH:7][C:6]=2[CH:5]=1)(=[O:23])[CH3:21]参加物
4
実験手順
A solution of 2.2 g (10 mmol) of 2-acetylphenanthrene in 50 mL of CH2Cl2 was stirred with 3.45 g (20 mmol) of m-chloro-peroxybenzoic acid for 3 h and allowed to stand for 93 h at room temperature. The solution was washed twice with 5% KOH solution and once with H2O, was dried and the solvent removed. From MeOH there was obtained 1.52 g of the title compound, m.p. 141°-142.5°.
後処理
- washThe solution was washed twice with 5% KOH solution and once with H2O
- customwas dried
- customthe solvent removed
出典と根拠
- ORDレコード
- ord-71eb5af273a54d328e5b64ab051361ef
- 出典データセット
- uspto-grants-1996_01
- 特許番号
- US05480913
反応ノート
読み込み中…