Tributylamine → 4-(Chloromethyl)benzyltri-n-butylammonium chloride

HRID 375023

反応式

HRID 375023 の反応式
[CH2:1]([N:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[Cl:14][CH2:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][Cl:23])=[CH:18][CH:17]=1>CO>[Cl-:14].[Cl:23][CH2:22][C:19]1[CH:20]=[CH:21][C:16]([CH2:15][N+:5]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:1][CH2:2][CH2:3][CH3:4])=[CH:17][CH:18]=1

参加物

4

反応物 2

HCID 7622TributylamineHCID 12171alpha,alpha'-Dichloro-p-xylene

生成物 1

HCID 867489774-(Chloromethyl)benzyltri-n-butylammonium chloride

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

A mixture of tri-n-butylamine (6 g, 32.2 mmol) and α,α'-dichloro-p-xylene (8.0 g, 46.0 mmol) in methanol (50 mL) was refluxed for 15 h after which time TLC examination showed completion of the reaction. Methanol was removed under reduced pressure to give an oily residue. The colorless oil was washed several times with toluene and hexane and then dried. The product obtained was used without further purification.

後処理

  1. temperaturewas refluxed for 15 h after which time TLC examination
  2. customcompletion of the reaction
  3. customMethanol was removed under reduced pressure
  4. customto give an oily residue
  5. washThe colorless oil was washed several times with toluene and hexane
  6. customdried
  7. customThe product obtained
  8. customwas used without further purification

出典と根拠

ORDレコード
ord-bce55896643248c297bd6e26e3da7f7e
出典データセット
uspto-grants-1996_01
特許番号
US05484556

関連ノート

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