反応式
[N:1]([CH2:4][C:5]1[O:9][C:8]([CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:7][CH:6]=1)=[N+]=[N-]>C(O)C.[Ni]>[NH2:1][CH2:4][C:5]1[O:9][C:8]([CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:7][CH:6]=1参加物
4
実験手順
Treatment of a solution in ethanol (50 mL) at ambient temperature of 5-azidomethyl-2-carboxyethylfuran (585 mg, 3.00 mmol), prepared as in step 3, with Raney nickel 2800 and 4 atmospheres of H2 for 24 hours, followed by filtration of the reaction mixture and concentration in vacuo gave 5-aminomethyl-2-carboxyethylfuran (0.50 g) as a yellow oil.
後処理
- filtrationfollowed by filtration of the reaction mixture and concentration in vacuo
出典と根拠
- ORDレコード
- ord-6f66f430e4d846f59b020b67e134241f
- 出典データセット
- uspto-grants-1996_01
- 特許番号
- US05486525
関連ノート
読み込み中…