1,3-Dioxane, 2-(2-bromoethyl)- → N-[2-(1,3-dioxane-2-yl)ethyl]-4-(4-methylstyryl)-quinolinium bromide

HRID 376466

反応式

HRID 376466 の反応式
[CH3:1][C:2]1[CH:19]=[CH:18][C:5]([CH:6]=[CH:7][C:8]2[C:17]3[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=3)[N:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[Br:20][CH2:21][CH2:22][CH:23]1[O:28][CH2:27][CH2:26][CH2:25][O:24]1>C(OC(=O)C)C>[Br-:20].[O:24]1[CH2:25][CH2:26][CH2:27][O:28][CH:23]1[CH2:22][CH2:21][N+:11]1[C:12]2[C:17](=[CH:16][CH:15]=[CH:14][CH:13]=2)[C:8]([CH:7]=[CH:6][C:5]2[CH:4]=[CH:3][C:2]([CH3:1])=[CH:19][CH:18]=2)=[CH:9][CH:10]=1

参加物

4

反応物 2

HCID 5206561,3-Dioxane, 2-(2-bromoethyl)-HCID 541720844-(4-Methylstyryl)quinoline

生成物 1

HCID 70262692N-[2-(1,3-dioxane-2-yl)ethyl]-4-(4-methylstyryl)-quinolinium bromide収率 70%

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒

実験手順

4-(4-methylstyryl)quinoline (0.245 g) and 2-(2-bromoethyl) 1,3-dioxane (0.195 g) were mixed and refluxed in ethylacetate (1.5 ml) for 18 hours. Yellow-green precipitate was separated by filtration, washed with ethyl ether and dried in vacuo to give 0.308 g of N-[2-(1,3-dioxane-2-yl)ethyl]-4-(4-methylstyryl)-quinolinium bromide.

後処理

  1. customYellow-green precipitate was separated by filtration
  2. washwashed with ethyl ether
  3. customdried in vacuo

出典と根拠

ORDレコード
ord-4d646bf149474aefa20541ab75a3405f
出典データセット
uspto-grants-2000_02
特許番号
US06020436

関連ノート

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