3-Phenylprop-2-Enal → (E,E)-2-(benzylaminocarbonyl)-3-styrylacrylonitrile
反応式
[CH:1](=O)[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[C:11]([CH2:13][C:14]([N-:16][CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)=[O:15])#[N:12]>>[CH2:17]([NH:16][C:14](/[C:13](=[CH:1]/[CH:2]=[CH:3]/[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)/[C:11]#[N:12])=[O:15])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1参加物
3
実験手順
The compound was prepared as described in Example 3 by adding cinnamaldehyde (0.048 ml, 0.38 mmol) to N-(cyanoacetyl)benzylamide (Example 4, 0.066 g, 0.38 mmol). After refluxing for 1 h and recrystallization from ethanol a white solid was obtained (0.074 g, 68%). The product gave the following analytical data:
後処理
- customThe compound was prepared
- temperatureAfter refluxing for 1 h
- customrecrystallization from ethanol a white solid
- customwas obtained (0.074 g, 68%)
- customThe product gave the following analytical data
出典と根拠
- ORDレコード
- ord-362fc3e8426c48ebb32387ada05775b4
- 出典データセット
- uspto-grants-2004_10
- 特許番号
- US06800659B2
反応ノート
読み込み中…