4-Methyl-N-(4-nitrophenyl)benzenamine → N1-(p-Tolyl)benzene-1,4-diamine

HRID 393518ノート

反応式

HRID 393518 の反応式
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][CH:10]=2)=[CH:4][CH:3]=1>C(O)C.[Pd]>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([NH2:15])=[CH:11][CH:10]=2)=[CH:4][CH:3]=1

参加物

4

反応物 1

HCID 948594-Methyl-N-(4-nitrophenyl)benzenamine

生成物 1

HCID 4764072N1-(p-Tolyl)benzene-1,4-diamine収率 85%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

Reduction of the nitro function of N-(4-methylphenyl)-4-nitroaniline (Indian J. Chem. (1981) 20B, 611-613) is carried out in the presence of Pd/C in ethanol, under the conditions described for intermediate 2.2. A grey solid is obtained with a yield of 85%.

後処理

  1. customA grey solid is obtained with a yield of 85%

出典と根拠

ORDレコード
ord-de7aa472744a4ea4b4f84072b3b427d5
出典データセット
uspto-grants-2004_10
特許番号
US06809090B2

反応ノート

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