化工社化工社 化学情報印刷レポート · 研究参考用
Jineol → 3,8-Dimethoxy quinoline
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Jineol | HCID 177338 | — |
| 反応物 | Diazomethane diethylether | HCID 21186548 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 3,8-Dimethoxy quinoline | HCID 10583798 | 80% |
反応手順
Jineol of 4.5 mg was dissolved in 2 ml of ethanol, and diazomethane ether solution was slowly dropped to the solution. After the excess of diazomethane and solvent was removed by purging with nitrogen gas, the solution was purified by silicagel chromatography to give 4.2 mg of 3,8-dimethoxy quinoline with 80% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05824689 |
| 出典データセット | uspto-grants-1998_10 |
| ORD ID | ord-a3d35d944aca43608a8e9c356519b602 |
| 出典メモ | uspto-grants-1998_10 |