Hydroxide → Diphenyldiethylphosphonium hydroxide

HRID 40426

反応式

HRID 40426 の反応式
[I-].[C:2]1([P+:8]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)([CH2:11][CH3:12])[CH2:9][CH3:10])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH-:19]>O>[OH-:19].[C:13]1([P+:8]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)([CH2:11][CH3:12])[CH2:9][CH3:10])[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

参加物

4

反応物 2

HCID 961HydroxideHCID 357429Phosphonium, diethyldiphenyl-, iodide

生成物 1

HCID 18407746Diphenyldiethylphosphonium hydroxide収率 96%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

This 98.45 g of diphenyldiethylphosphonium iodide was then dissolved in water, and converted to the corresponding hydroxide with 270 g of an anionic exchange resin in batch overnight, yielding 271.75 g of a 0.94 M solution of diphenyldiethylphosphonium hydroxide (96% of exchange yield) The diphenyldiethylphosphonium hydroxide was used as SDA source.

出典と根拠

ORDレコード
ord-2249a546e80243079730b7f18d3febb6
出典データセット
uspto-grants-2013_09
特許番号
US08529868B2

関連ノート

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