Pyridine → Borate(1-), tetrafluoro-, hydrogen, compd. with pyridine (1:1:1)

Tetrafluoroboric acid (250 ml, 2.00 mol) was added to cool (0° C.) pyridine (157.7 ml, 1.95 mol) within 25 min obtaining a colorless precipitate. After the acid was completely added the mixture was further stirred for 30 min at the same temperature. Then the reaction mixture was filtered. The residue was washed twice with cold ethanol and dried 12 h at high vacuum to yield 201.9 g (60%) pyridinium tetrafluoroborate as colorless crystals.

1. customobtaining a colorless precipitate
2. additionAfter the acid was completely added the mixture
3. filtrationThen the reaction mixture was filtered
4. washThe residue was washed twice with cold ethanol
5. customdried 12 h at high vacuum

ORDレコード

ord-79801c72926e4e53b33ff500a6e9e9fd

出典データセット

uspto-grants-2014_06

DOI

10.6084/m9.figshare.5104873.v1

特許番号

US08754111B2