Mesitylene → Bis(eta-cyclopentadienyl) iron

HRID 408052

反応式

HRID 408052 の反応式
[C:1]1([CH3:9])[CH:6]=[C:5]([CH3:7])C=C(C)C=1.C([C-:12]1[CH:16]=[CH:15][CH:14]=[CH:13]1)=C.[CH-]1C=CC=C1.[Fe+2:22].[C-]1(C=O)C=CC=C1.[CH-]1C=CC=C1.[Fe+2]>>[CH-:5]1[CH:6]=[CH:1][CH:9]=[CH:7]1.[CH-:12]1[CH:16]=[CH:15][CH:14]=[CH:13]1.[Fe+2:22]

参加物

4

反応物 3

HCID 7947MesityleneHCID 15184314Ferrocenecarboxyaldehyde2 回HCID 15807218Cyclopenta-1,3-diene;5-ethenylcyclopenta-1,3-diene;iron(2+)2 回

生成物 1

HCID 7611Bis(eta-cyclopentadienyl) iron

反応条件

温度
150 °C

実験手順

Approximately 10 mmol mesitylene solution of vinylferrocene (VFc) or ferrocenecarboxaldehyde (FcA) was put in a round bottom flask and bubbled with nitrogen or argon gas for at least 30 min. A piece of the H-terminated silicon substrate was then immersed in the solution and allowed to react with VFc or FcA for about 12 h under reflux at about 150° C. in an oil bath. During the reaction, the solution was also purged with nitrogen (or argon) to eliminate dissolved oxygen and to prevent the substrate from being oxidized. After the reaction, the substrate derivatized with VFc or FcA was rinsed with dichloromethane, acetonitrile, and methanol; and dried under a stream of nitrogen gas. The derivatization of the H-terminated surface with ferrocene moieties as described in Example 2 is illustrated in FIG. 5.

後処理

  1. custombubbled with nitrogen or argon gas for at least 30 min
  2. customto react with VFc or FcA for about 12 h
  3. customDuring the reaction
  4. customthe solution was also purged with nitrogen (or argon)
  5. dissolutionto eliminate dissolved oxygen
  6. customAfter the reaction
  7. washwas rinsed with dichloromethane, acetonitrile, and methanol
  8. customand dried under a stream of nitrogen gas

出典と根拠

ORDレコード
ord-9b8f4d7ad4174ee1b78975c22da0caae
出典データセット
uspto-grants-2014_06
特許番号
US08758584B2

関連ノート

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