Formaldehyde → (1R,5R)-10-hydroxymethyl-2-pinene

反応式

[CH3:1][C:2]1([CH3:10])[CH:8]2[CH2:9][CH:3]1[CH2:4][CH2:5][C:6]2=[CH2:7].[CH2:11]=[O:12]>>[OH:12][CH2:11][CH2:7][C:6]1[C@@H:8]2[CH2:9][C@@H:3]([CH2:4][CH:5]=1)[C:2]2([CH3:10])[CH3:1]

参加物

反応物 2

HCID 712Formaldehyde

HCID 14896Beta-Pinene

生成物 1

HCID 6978972(1R,5R)-10-hydroxymethyl-2-pinene

実験手順

A mixture of β-pinene (32 ml) and paraformaldehyde (4 g) in sealed tube was reacted for 18 hrs at 180° C. The reaction solution was distilled to give the title compound (15.5 g) having the following physical data:

後処理

customwas reacted for 18 hrs at 180° C
distillationThe reaction solution was distilled

出典と根拠

ORDレコード: ord-e68a368eafa94ffeb9e2294b9496f4e5
出典データセット: uspto-grants-1988_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04792550

反応ノート

読み込み中…