Hydrochloric Acid → 1,3,5-Tris-(p-(dec-1-yloxycarbonyl)-anilino)-s-triazine

HRID 4158

反応式

HRID 4158 の反応式
[NH2:1][C:2]1[CH:20]=[CH:19][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:4][CH:3]=1.[N:21]1[C:28](Cl)=[N:27][C:25](Cl)=[N:24][C:22]=1Cl.Cl>C1(C)C(C)=CC=CC=1>[CH2:9]([O:8][C:6]([C:5]1[CH:4]=[CH:3][C:2]([NH:1][N:21]2[CH2:28][N:27]([NH:1][C:2]3[CH:20]=[CH:19][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:4][CH:3]=3)[CH2:25][N:24]([NH:1][C:2]3[CH:3]=[CH:4][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:19][CH:20]=3)[CH2:22]2)=[CH:20][CH:19]=1)=[O:7])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 7954Cyanuric chlorideHCID 4446056Decyl 4-aminobenzoate

生成物 1

HCID 201527341,3,5-Tris-(p-(dec-1-yloxycarbonyl)-anilino)-s-triazine

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

反応条件

温度
90 °C

実験手順

83 g of decyl p-aminobenzoate and 18.5 g of cyanuric chloride in 1,000 ml of xylene were heated at 140° C. for 8 hours. After the evolution of hydrogen chloride was complete, the reaction solution was cooled to 90° C., washed twice with saturated sodium bicarbonate solution and once with water, and then cooled to room temperature. The white crystals precipitated were filtered off under suction and dried.

後処理

  1. washwashed twice with saturated sodium bicarbonate solution and once with water
  2. temperaturecooled to room temperature
  3. customThe white crystals precipitated
  4. filtrationwere filtered off under suction
  5. customdried

出典と根拠

ORDレコード
ord-d7ec7c5243894addb439002cd6f1f99a
出典データセット
uspto-grants-1988_02
特許番号
US04724137

関連ノート

読み込み中…