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Benzene, 1-chloro-4-ethynyl- → Z-4-chlorostyryl 2-chlorobenzylsulfide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene, 1-chloro-4-ethynyl- | HCID 70118 | — |
| 反応物 | 2-Chlorobenzyl mercaptan | HCID 580759 | — |
| 反応物 | Sodium | HCID 5360545 | — |
| 生成物 | Z-4-chlorostyryl 2-chlorobenzylsulfide | HCID 86588938 | — |
反応手順
A solution of 4-chlorophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-chlorostyryl 2-chlorobenzylsulfide. The title compound was obtained in 73% yield following oxidation. 1HNMR (CDC13) δ4.56 (2H, s), 6.70 (1H, d, JH,H=12.05), 7.18-7.64 (8H aromatic+1H ethylenic).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06656973B2 |
| 出典データセット | uspto-grants-2003_12 |
| ORD ID | ord-7d2388c45870420b822bfdc985adb262 |
| 出典メモ | uspto-grants-2003_12 |