HRID431149

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70118

Benzene, 1-chloro-4-ethynyl-

C8H5Cl

HCID580759

2-Chlorobenzenemethanethiol

C7H7ClS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Clc1ccc(/C=C\C(SC(/C=C\c2ccc(Cl)cc2)c2ccccc2Cl)c2ccccc2Cl)cc1$

HCID86588938

未命名化合物

PROCEDURE

实验过程

A solution of 4-chlorophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-chlorostyryl 2-chlorobenzylsulfide. The title compound was obtained in 73% yield following oxidation. 1HNMR (CDC13) δ4.56 (2H, s), 6.70 (1H, d, JH,H=12.05), 7.18-7.64 (8H aromatic+1H ethylenic).