Phosphoric Acid → 2-[(Octan-2-yl)oxy]ethan-1-ol
反応式
[CH2:1]([C:7]1([CH3:12])[O:11][CH2:10][CH2:9][O:8]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].P(=O)(O)(O)O>[Pd]>[CH3:12][CH:7]([O:8][CH2:9][CH2:10][OH:11])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]参加物
4
実験手順
2-Hexyl-2-methyl-1,3-dioxolane (30 g, 0.17 mol), the palladium catalyst (2) (2.2 g) and phosphoric acid (110 mg) were charged in a 70-mL autoclave, followed by a reaction under a hydrogen pressure of 10 MPa at 150° C. for 5 hours. After completion of the reaction, the catalyst was removed by filtration to obtain a crude product (29.7 g).
後処理
- customfollowed by a reaction under a hydrogen pressure of 10 MPa at 150° C. for 5 hours
- customAfter completion of the reaction
- customthe catalyst was removed by filtration
出典と根拠
- ORDレコード
- ord-45a7de8f03884b129f1c2c5dee235151
- 出典データセット
- uspto-grants-2003_12
- 特許番号
- US06657089B1
反応ノート
読み込み中…